Luc has sex with every lady, so it makes sense.
"Why not me?" is kinda a weird reaction, since he's up for it. Ha. Pun.
www.jrichardsingleton.blogspot.com

I think she's going to realize her feelings in the next few episodes, especially if mum goes after her to force Luci back to heavenn

I loved the look on her face when Dan called her on her jealousy and she tried so hard to pretend she wasn't. So busted!
"There is a crack in everything
That's how the light gets in" Leonard Cohen

I think he will always love Chloe but I think he knows that it is over

True, but I think he feels guilty for the whole palmetto ordeal and the things he's done. I think the fact that he was blaming Lucifer for the break up of his marriage proves he still has it for Chloe.

Not anymore. A few episodes back, when Chloe was agreeing to a trip with him, it was him who asked for a formal divorce.

I'm kind of surprised that Dan took it so well. I mean he was trying to get his wife back.

Jealous*