Actually, I don't think I have any of Myrna's films on DVD.

I actually feel like Myrna Loy is extremely well represented given that she is, arguably, a tier down from many of the other legends of her day. Indeed, check out The Thin Man set - it's truly superb, and the Myrna Loy/William Powell collection will give you a few of her other greats with Powell. Aside from that, quite a few of her other films are available individually - particularly if you are willing to invest in a multi-region player and import some. I have found that different countries seem to have different films available and it's better to buy a multi-region player and buy from all over the place than to spread yourself thin buying from only one market.
For instance, I bought a Katharine Hepburn set from Spain that featured almost all of her RKO films for the same price I would pay for a mere two of her RKO films from the Warner Archives.

Unfortunately like many Warner DVDs, the Powell/Loy has not been given a UK release. It's difficult to try and get a hold of these films in the UK.

Definitely any film (or Myrna Loy) lover should invest in the Myrna Loy and William Powell Collection.
Warner has done an excellent job with these films looking good. You will fall in love with Myrna all over again watching here in the excellent drama Evelyn Prentice.
Also search out the excellent Prizefighter and the Lady (she is awesome). Penthouse is a goodie (although not my favorite).
And I LOVE the Thin Man box set!!
Once again, Warner has got these films looking really good for their age.
Myrna Loy is the reason I love films. She is the greatest underrated actress to come out of Hollywood. I am thankful that home video preserves her work for us to cherish for many years!

I've been trying to stay inside the 1930s and take in as much as I could before I moved on to her later work in the 40s and beyond, but I appreciate your suggestions. Next time I get a chance I'm going to try to pick up a few of those DVDs. Especially that Myrna Loy/William Powell collection, I've been eyeballing that one for a while now.
"Ram this in your clambake, bitchcakes!"

Fortunately, comparing to many of her contemporaries, I'd say there's a rather reasonable amount of Myrna movies released on official DVDs, not to mention the lots released through Warner Archives Collection.
http://www.amazon.com/Myrna-Loy-William-Powell-Collection/dp/B009da00XPGU M/ref=sr_1_1?s=movies-tv&ie=UTF8&qid=1406989259&sr=1-1& ;keywords=myrna+loy
http://www.amazon.com/Bachelor-Bobby-Soxer-Cary-Grant/dp/B0001WTWRY/re f=sr_1_9?s=movies-tv&ie=UTF8&qid=1406989259&sr=1-9&key words=myrna+loy
http://www.amazon.com/Mr-Blandings-Builds-Dream-House/dp/B0001WTWVU/re f=sr_1_27?s=movies-tv&ie=UTF8&qid=1406989380&sr=1-27&k eywords=myrna+loy
http://www.amazon.com/Great-Ziegfeld-William-Powell/dp/B0045HCIZO/ref= sr_1_29?s=movies-tv&ie=UTF8&qid=1406989403&sr=1-29&key words=myrna+loy
http://www.amazon.com/Terrace-Paul-Newman/dp/B00008MTW0/ref=sr_1_31?s= movies-tv&ie=UTF8&qid=1406989431&sr=1-31&keywords=myrn a+loy
There's also "Arrowsmith" (1931) and "The Jazz Singer" (1927), which are far from being "Myrna Loy movies", but in the former she shows up for a few minutes, and in the latter less than 20 seconds. However, it's always interesting to see her before reaching stardom.
Animal crackers in my soup
Monkeys and rabbits loop the loop

I have two of her later movies on DVD, "Ants" (a tv movie) and "Airport 75". I also know the Burt Reynolds movie "The End" which she appears in is on DVD. "Cheaper By the Dozen" and "The Best Years of Our Lives" are also on DVD.

After doing some digging I've uncovered quite a few of her movies on DVD. Most of them are DVD-Rs from Warner Archive, but at least they're official releases. I guess it was just a little overwhelming trying to tackle some of her massive filmography being a new fan.